I can guess what microcontroller you're talking about from the diagram (ATmega168 or maybe an ATmega8?), but note that it helps if you mention this crucial information explicitly. The datasheet for your microcontroller has all of this information, so you might want to consider reading through the ADC portion.
PC0 = ADC channel 0
...
PC5 = ADC channel 5
ADC6 = ADC channel 6
ADC7 = ADC channel 7